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Silicon Carbide Substrate Processing and Surface Condition Analysis

published on 2025-11-14

— Surface Roughness and Application Analysis of Multi-wire Slicing, Grinding, and CMP Polishing


I. Characteristics and Processing Challenges of Silicon Carbide

Silicon carbide (SiC) is a third-generation wide-bandgap semiconductor material known for its superior thermal, mechanical, and electrical properties. It is widely used in high-end applications such as new energy vehicles, rail transit, 5G communication, and aerospace.
Property Typical Value
(4H-SiC, room temperature)
Description
Mohs hardness 9.2 – 9.3 Second only to diamond
Thermal conductivity 490 W/m·K Excellent heat dissipation
Bandgap width 3.26 eV Wide bandgap feature
Breakdown field 2.8 MV/cm About 10× higher than silicon

However, these same characteristics also bring extreme processing difficulties.
Summary:
Due to its high hardness and chemical stability, SiC is far more difficult to process than silicon. This requires extremely precise control of process parameters and equipment performance.


II. SiC Substrate Processing Chain

The typical SiC wafer processing sequence is:
Crystal growth Orientation and rounding Multi-wire slicing Grinding CMP polishing Cleaning and inspection
Each subsequent step is designed to remove the surface and subsurface damage caused by the previous process, gradually improving the surface quality to an atomically flat level.


III. Multi-Wire Slicing: Shaping and Initial Surface Formation

Principle

Multi-wire slicing uses a high-speed diamond wire to cut SiC ingots into thin wafers.
Material removal occurs in the brittle regime, where SiC fractures and chips due to its extreme hardness.


Surface Condition

Macroscopic: Clear cutting marks and directional textures.
Microscopic: Numerous microcracks, fractures, and pits. Damage depth can reach 10–20 μm.


Surface Roughness

Ra = 0.8 – 2.5 μm (800–2500 nm)


Application Analysis

Status: Sliced wafers cannot be used directly for device fabrication or epitaxy.
Purpose: To shape the wafer and control thickness, providing material allowance for subsequent grinding.


IV. Grinding: Damage Removal and Surface Flattening

Principle

Grinding uses diamond slurry and a grinding plate to remove the damaged layer left by slicing.
This process marks the transition from brittle to plastic material removal, though brittle mode still dominates.


Surface Condition

Macroscopic: Uniform matte appearance; cutting marks are removed.
Microscopic: Deep cracks are eliminated, but fine scratches and shallow grooves remain.
The new plastic damage layer is typically 2–5 μm deep.


Surface Roughness

Ra = 0.2 – 0.8 μm (200–800 nm)


Application Analysis

Purpose: To remove slicing damage and improve flatness, preparing for CMP.
Status: A semi-finishing step — not suitable for high-end epitaxy.
Special case: Can be used for the backside of power devices where surface requirements are lower.


V. CMP Polishing: Achieving Atomically Smooth, Damage-Free Surfaces

Principle

Chemical Mechanical Polishing (CMP) combines chemical reactions and mechanical removal:
Chemical action: Alkaline slurry reacts with SiC to form a soft SiO₂ layer.
Mechanical action: Polishing pad and nanoscale abrasives remove this layer cyclically.
This process occurs mainly in the plastic regime, introducing almost no new mechanical damage.


Surface Condition

Macroscopic: Mirror-like finish with clear reflections.
Microscopic: Atomic step-flow structures observed under AFM; no cracks or deformation layers.


Surface Roughness

Ra < 0.5 nm (premium products < 0.2 nm)


Application Analysis

Status: Final usable condition for high-end device manufacturing.
Applications:
Power electronics (EVs, rail transit, smart grids)
RF devices (5G base stations, radar systems)
High-temperature electronics (aerospace, oil exploration)
LED substrates (for high-brightness GaN-based LEDs)


VI. Process Comparison and Performance Summary

Process Stage Surface Description Roughness
(Ra)
Damage Depth Main Function Application Status
Multi-wire slicing Visible cutting marks, microcracks 0.8–2.5 μm 10–20 μm Shaping and thickness control Requires further processing
Grinding Matte surface, uniform scratches 0.2–0.8 μm 2–5 μm Remove slicing damage Semi-finishing
CMP polishing Mirror surface, atomically smooth <0.5 nm None Achieve atomically flat surface Final usable state
 
 

VII. Conclusion and Insights

The SiC substrate processing chain is essentially a progressive refinement process, where each stage removes the damage from the previous one and reduces surface roughness step by step.
From multi-wire slicing to CMP, the process transforms the surface from a brittle, damaged state to a mirror-like, defect-free finish.
CMP polishing enables SiC substrates to reach atomic-level flatness and stability, providing the essential foundation for high-performance device fabrication.
碳化硅2

Core Insight:
SiC substrate processing is not merely a competition of machining precision—it is an integration of material science, process control, and surface engineering.
With continuous innovation in CMP chemistry and automation, the yield and efficiency of SiC substrates will keep improving, driving the rapid advancement of the third-generation semiconductor industry.
 

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